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REVISION NOTES

IGCSE Edexcel Chemistry

4.1 Introduction

4.1.1 Know that a hydrocarbon is a compound of hydrogen and carbon only

Hydrocarbon is a compound containing hydrogen and carbon only.

4.1.2 Understand how to represent organic molecules using empirical formulae, molecular formulae, general formulae, structural formulae and displayed formulae

  • Empirical formula shows the simplest whole number ratio of atoms
  • Molecular formula shows the actual number of atoms 
  • General formula shows a ratio of atoms in a family of compounds in terms of ‘n’ where n is a varying whole number
  • Simplified Structural formula shows the way in which atoms are bonded (Structure), but not all bonds
  • Displayed Structural formula shows all atoms and bonds in a molecule

4.1.3 Know what is meant by the terms homologous series, functional group and isomerism

HOMOLOGOUS SERIES

  • Series of compounds with:
    • Same functional group
    • Same general formula
    • Similar chemical properties
    • Gradually increasing physical properties along the series (e.g. boiling point)

FUNCTIONAL GROUP

  • A group of atoms present in the compound
  • It is a distinctive combination of atoms in the compound
  • It is responsible for the chemical reactions of a compound

ISOMERISM

  • Compounds with: 
    • Same molecular formula 
    • But different structural formula 
    • Due to different arrangements of atoms

More will be discussed throughout this topic.

4.1.4 Understand how to name compounds relevant to this specification using the rules of international Union of Pure and Applied Chemistry (IUPAC) nomenclature students will be expected to name compounds containing up to six carbon atoms

PREFIXES (BEGINNING OF THE NAME)

  • Depends on the number of carbons in the parent chain – parent chain is the longest continuous carbon chain
  • 1C – Meth
  • 2C – Eth
  • 3C – Prop
  • 4C – But
  • 5C – Pent
  • 6C – Hex

SUFFIXES

  • Refers to the functional group
  • Alkanes – ane
  • Alkenes – ene
  • Alcohol – ol
  • Carboxylic acids – anoic acid
  • Esters – yl, anoate

4.1.5 Understand how to write the possible structural and displayed formulae of an organic molecule given its molecular formula

If the molecular formula given is C2H6:

  • Structural formula: CH3CH3
  • Displayed formula:

Be aware of isomers

  • Different structural formula and displayed formula can be drawn from same molecular formula

Example: C5H12

To name the alkane isomers: 

Consider the number of carbons in the longest continuous carbon chain.

Know that the CH3 group is called the “methyl” group .

edexcel_igcse_chemistry_topic 21_introduction_001_isomers of alkane C5H12

4.1.6 understand how to classify reactions of organic compounds as substitution, addition and combustion

Knowledge of reaction mechanisms is not required

ADDITION REACTIONS

  • Involve only one product
  • 2 reactants → 1 product
  • E.g. ethene + hydrogen → ethane

SUBSTITUTION REACTIONS

  • Involve two products
  • 2 reactants → 2 products
  • Hydrogen chloride + ethanol → chloroethane + water
    (Cl replaces OH, they swap places)

COMBUSTION REACTIONS

  • Involves the reaction of a fuel with oxygen
  • Complete combustion of hydrocarbon produces water and carbon dioxide
  • Incomplete combustion of hydrocarbon produces water and carbon monoxide
Back
Next
1. Principles of Chemistry

1.1 State of Matter

1.2 Elements, Compounds and Mixtures

1.3 Atomic Structure

1.4 The Periodic Table

1.5 Chemical Formulae, Equations and Calculations

1.6 Ionic Bonding

1.7 Covalent Bonding

1.8 Metallic Bonding

1.9 Electrolysis

2. Inorganic Chemistry

2.1 Group 1 (Alkali Metals) – Lithium, Sodium and Potassium

2.2 Group 7 (Halogens) – Chlorine, Bromine and Iodine

2.3 Gases in the Atmosphere

2.4 Reactivity Series

2.5 Extraction and Uses of Metals

2.6 Acids, Alkalis and Titrations

2.7 Acids, Bases and Salt Preparations

2.8 Chemical Tests

3. Physical Chemistry

3.1 Energetics

3.2 Rates of Reaction

3.3 Reversible Reactions and Equilibria

4. Organic Chemistry

4.1 Introduction

4.2 Crude Oil

4.3 Alkanes

4.4 Alkenes

4.5 Alcohols

4.6 Carboxylic Acids

4.7 Esters

4.8 Synthetic Polymers

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